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Title: Biofilm-induced changes of soil organic matter structure and the
resulting impact on the bioavailability of sorbed 2,4,6-trinitrotoluene and its
amine metabolites
Period: 1999-2003
Goals: The goals of this research are to 1) characterize SOM structure as a function of (a) sorbed density, and (b) exposure to various solution chemistries; 2) quantify the dependence of desorption and biotransformation kinetics of SOM-bound NATs on SOM structure; and 3) quantify differences in NAT biotransformation kinetics in systems where the only system variable is the potential for biofilm formation.
Our goals for the future are to obtain detailed knowledge about adsorption kinetics of trinitrotoluene, aminodinitrotoluene, diaminonitrotoluene, and triaminotoluene onto soil humic acid by using state of the art imaging chemical analysis instrumentation and to relate the observed surface chemistry to microbial transformation rates of TNT.
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